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Pavleta Knutsson

Capabilities

What the group can do

Few groups can follow a material from a 12 MW boiler to the electron microscope. These are the facilities and methods behind the work.

  1. 01

    Real plant conditions

  2. 02

    Controlled laboratory exposures

  3. 03

    Microscopy, diffraction and modelling

Large-scale facilities

Research gasifier and 12 MW boiler at Chalmers
Bed-material and ash studies under real operating conditions, from 5 to more than 300 hours of exposure in the Chalmers 12 MW circulating fluidized-bed boiler and the 2–4 MW research gasifier, connected to the GoBiGas experience.
100 kW chemical-looping combustor
Interconnected fluidized beds for testing oxygen carriers such as ilmenite with solid fuels, used in the chemical-looping work.

Laboratory reactors

Laboratory fluidized-bed reactorsPlaceholder
Lab-scale reactors in which ash model compounds (for example K2CO3 or KH2PO4) are added to oxygen carriers while fuel conversion and fluidization are monitored.
Corrosion exposures, including gaseous alkaliPlaceholder
Exposures to gaseous Na2SO4 and KOH(g) that imitate the environment in boilers and chemical-looping air reactors.

Characterisation

Scanning electron microscopy (SEM)Placeholder
Cross-sections of oxide scales, deposits and bed particles at micrometre to nanometre scale, with elemental mapping to follow how K, Ca, Fe and Ti move.
X-ray diffraction (XRD)Placeholder
Phase identification in corrosion products, ash layers and bed materials, for example KTi8O16 in potassium-loaded ilmenite.
Thermodynamic modelling
Equilibrium calculations used alongside microscopy to propose mechanisms for ash–bed material interaction.

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